Search results for "isotope geochemistry"
showing 10 items of 23 documents
Multiple intrusive phases in the Leinster Batholith, Ireland: geochronology, isotope geochemistry and constraints on the deformation history
2017
The formation of granite batholiths, commonly by incremental assembly of small magma batches, and their correlation with tectonic events, on both local and regional scales, is crucial to understanding the evolution of the Earth9s continental crust. However, these correlations often rely on assumptions about the detailed relationship and timing of mapped units. Here we report how an integrated geochronological, structural and isotope geochemical study in only one key locality from the late Caledonian Leinster Batholith in SE Ireland provides the potential for unravelling essential questions on batholith petrogenesis. The Northern Unit of the Leinster Batholith intruded incrementally, as demo…
8.2 ka event North Sea hydrography determined by bivalve shell stable isotope geochemistry.
2019
AbstractThe abrupt 8.2 ka cold event has been widely described from Greenland and North Atlantic records. However, its expression in shelf seas is poorly documented, and the temporal resolution of most marine records is inadequate to precisely determine the chronology of major events. A robust hydrographical reconstruction can provide an insight on climatic reaction times to perturbations to the Atlantic Meridional Overturning Circulation. Here we present an annually-resolved temperature and water column stratification reconstruction based on stable isotope geochemistry of Arctica islandica shells from the Fladen Ground (northern North Sea) temporally coherent with Greenland ice core record…
Data for: Refining the temperature dependence of the oxygen and clumped isotopic compositions of structurally bound carbonate in apatite
2020
Compilation of all measured and calculated data from equilibrated gases and empirical transfer functions (I.), standard (II.) and sample (III.) measurements including δ47 and raw Δ47 values. Comparison of [Brand] processed Δ47 values of ETH-1, ETH-2, and ETH-3 with Δ47 values from prior studies (IV.).The sample materials (III.) are: Synthetic hydroxyapatites, tooth enamel(oid) and dentine from African elephant (Loxodonta africana) and Greenland shark (Somniosus microcephalus), sand tiger shark tooth dentine (Carcharias taurus), and megatooth shark tooth enameloid (Carcharodon megalodon). THIS DATASET IS ARCHIVED AT DANS/EASY, BUT NOT ACCESSIBLE HERE. TO VIEW A LIST OF FILES AND ACCESS THE F…
Sedimentology and isotope geochemistry of Carnian deep-water marl/limestone deposits from the Sicani Mountains, Sicily: Environmental implications an…
1995
Abstract The upper Triassic Halobia-bearing marl/limestone deposits from the Sicani Mountains (Sicily) record the sedimentary evolution of the Sicanian Basin through the middle and late Carnian time. Dark marls and interbedded grey calcilutites of Julian age are characterized by abundant pyrite, sparse bioturbation and negative carbonate carbon δ13C values. They accumulated in a basin with dominantly anoxic to dysaerobic bottom waters. Lower Tuvalian dark-grey pyritic marls and calcilutites, which contain carbonate minerals with relatively high Mn contents and widely fluctuating δ13C signatures, were deposited under dysaerobic conditions. Middle and upper Tuvalian cherty limestones show int…
Dissolution and precipitation of gypsum and carbonate minerals in soils on evaporite deposits, central Sicily: isotope geochemistry and microfabric a…
1993
Abstract Soil profiles developed from carbonate- and sulphate-rich deposits of the Gessoso-Solfifera Formation (Miocene) were sampled in central Sicily (544 mm annual precipitation and a strongly seasonal rainfall regime). Carbon and oxygen isotope data supported by mineralogical and thin section investigations indicate that meteoric waters and groundwaters dissolve and repricipitate carbonates and gypsum in the soil profiles. The boundary between the C horizon and the overlying one is the formation site of 18O depleted carbonates (calcite and/or dolomite) presumably precipitated from percolating waters during wet periods. Greater δ18O values of carbonates in the shallower horizons suggest …
Textural features and isotope geochemistry of the Scillato travertine (north-central Sicily): genetic implications.
2015
The travertine deposit, outcropping near the Scillato town (north-central Sicily), was originated by precipitation of calcium carbonate from the Scillato springs, documented as bicarbonate-enriched waters due to dissolution of the Madonie mountains carbonate rocks. This deposit is today well represented by the Travertine Cave, essentially constituted by stalactites and stalagmites in which travertine typically appears laminated with alternation of light and dark laminae. Mineralogical analysis have revealed the almost exclusive presence of calcite and observation under the polarized-light microscope showed different textural features, like presence of debris and porous portions, micritic po…
Are oxygen isotope fractionation factors between calcite and water derived from speleothems systematically biased due to prior calcite precipitation …
2021
Abstract The equilibrium oxygen isotope fractionation factor between calcite and water (18αcalcite/H2O) is an important quantity in stable isotope geochemistry and allows in principle to infer temperature variations from carbonate δ18O if carbonate formation occurred in thermodynamic equilibrium. For this reason, many studies intended to determine the value of the oxygen isotope fractionation factor between calcite and water (18αcalcite/H2O) for a wide range of temperatures using modern cave calcite and the corresponding cave drip water or ancient speleothem carbonate and fluid inclusion samples. However, the picture that emerges from all of these studies indicates that speleothem calcite i…
Zircon ages of late Palaeoproterozoic (ca. 1.72–1.70Ga) extension-related granitoids in NE Rajasthan, India: Regional and tectonic significance
2011
Abstract The Khetri region forms a late Palaeoproterozoic igneous–metamorphic complex in NE Rajasthan, India. Seven granitoid plutons of the Khetri complex have been studied for zircon U–Pb and Pb–Pb dating along with whole-rock and Nd–Sr isotope geochemistry to provide new constraints on the Palaeoproterozoic magmatic activity in the Aravalli orogen of northwestern India. Most intrusives show evidence of moderate to extreme albitisation forming microcline–albite granite and albite granite, respectively. The rocks are metaluminous to weakly peraluminous, largely ferroan and intraplate A-type granites. The U–Pb zircon ages for four plutons cover a time span of 1732–1682 Ma, whereas Pb–Pb zir…
The tectonic domains of southern and western Madagascar
2019
Abstract Southern and western Madagascar is comprised of five tectonic provinces that, from northeast to southwest, are defined by the: (i) Ikalamavony, (ii) Anosyen, (iii) Androyen, (iv) Graphite and (v) Vohibory Domains. The Ikalamavony, Graphite and Vohibory Domains all have intermediate and felsic igneous protoliths of tonalite-trondhjemite-granodiorite-granite composition, with positive eNd, and low Sr and Pb isotopic ratios. All three domains are interpreted to be the products of intra-oceanic island arc magmatism. The protoliths of the Ikalamavony and Graphite Domains formed repectively between c. 1080–980 Ma and 1000–920 Ma, whereas those of the Vohibory Domain are younger and date …
Age and isotope geochemistry of the Archaean Pongola and Usushwana suites in Swaziland, southern Africa: a case for crustal contamination of mantle-d…
1984
The igneous rocks of the Pongola Supergroup (PS) and Usushwana Intrusive Suite (UIS) represent a case of late Archaean continental magmatism in the southeastern part of the Kaapvaal craton of South Africa and Swaziland. U-Pb dating on zircons from felsic volcanic rocks of the PS yields a concordia intercept age of 2940 ± 22Ma that is consistent with a Sm-Nd whole rock age of 2934 ± 114Ma determined on the PS basalt-rhyolite suite. The initial eNd of−2.6 ± 0.9 is the lowest value so far reported for Archaean mantle-derived rocks. Rb-Sr whole rock dating of the PS yields a younger isochron age of 2883 ± 69Ma, which is not significantly different form the accepted U-Pb zircon age. An internal …